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The first step aren’t easy even when it comes to studying tools with intuitive interface like Substance Painter. Character artist Andrew Smith has published a video tutorial on learning the basics of the tool by Allegorithmic. A really nice and easy way to start using one of the most popular texturing solutions.
The artist has also contributed to an article by Allegorithmic on using particle brushes inside SP for character art in Farpoint. You can find the full tutorial here.
Also, make sure to check out his website to look at his other projects.